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Novel strategies to tailor the photocatalytic activity of metal–organic frameworks for hydrogen generation

Luis A. ALFONSO-HERRERA, Leticia M. TORRES-MARTINEZ, J. Manuel MORA-HERNANDEZ

Frontiers in Energy 2022, Volume 16, Issue 5,   Pages 734-746 doi: 10.1007/s11708-022-0840-x

Abstract: strategies employed to increase the efficiency of metal–organic framework (MOF)-based systems toward the photocatalytichydrogen evolution (PHE) reaction through specific strategies: tailoring the photocatalytic activityAlthough several reviews have investigated the photocatalytic activity of MOFs from a general point ofHowever, they did not consider the interactions between the components of the photocatalytic materialThis study highlights the effects of strength of the supramolecular interactions on the photocatalytic

Keywords： metal–organic frameworks (MOFs)     photocatalytic hydrogen evolution     MOF heterojunctions     materials derived    

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Enhanced hydrogen production from aqueous methanol solution using TiO

Paramasivan GOMATHISANKAR,Tomoko NODA,Hideyuki KATSUMATA,Tohru SUZUKI,Satoshi KANECO

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 2,   Pages 197-202 doi: 10.1007/s11705-014-1417-y

Abstract: The photocatalytic hydrogen production from aqueous methanol solution using titanium dioxide (TiO ) wasThe results show that only the addition of copper particles enhances the hydrogen production.Under the optimal conditions, the hydrogen production using TiO /Cu as photocatalysts is approximately

Keywords： photocatalytic hydrogen generation     methanol     copper particles     TiO2     metal-semiconductor interface    

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Design and synthesis of ZnCoO/CdS for substantially improved photocatalytic hydrogen production

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 5,   Pages 606-616 doi: 10.1007/s11705-022-2233-4

Abstract: In this study, the hydrogen evolution performance of CdS nanorods is improved using ZnCo2OAccording to the experimental results of photocatalytic hydrogen evolution, the final hydrogen evolutionZnCo2O4 expands the adsorption range of light and improves the performance of photocatalytichydrogen evolution.

Keywords： ZnCo2O4 nanosphere     CdS nanorods     photocatalytic hydrogen evolution    

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Function-reversible facets enabling SrTiO nanocrystals for improved photocatalytic hydrogen evolution

Frontiers in Energy doi: 10.1007/s11708-023-0894-4

Abstract: facets with different band levels contribute to promoted charge separation, and provide active sites for photocatalyticIn such cases, only one family of facets can be used for photocatalytic hydrogen evolution.hydrogen via chemically depositing Pt nanoparticles on all facets.hydrogen evolution after depositing Pt nanoparticles, together with the {001} facets.Thus, the full-facets-utilization led to a much-improved activity for photocatalytic hydrogen, in contrast

Keywords： SrTiO3 nanocrystals     crystal facets     photocatalysis     hydrogen evolution    

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Recent advances of hydrogen production through particulate semiconductor photocatalytic overall water

Frontiers in Energy 2022, Volume 16, Issue 1,   Pages 49-63 doi: 10.1007/s11708-022-0817-9

Abstract: Solar energy-driven photocatalytic water splitting has been investigated for decades to produce cleanand renewable green hydrogen.the cutting-edge research within the overall water splitting system is summarized from the one-step photocatalyticIn addition, the photocatalytic reaction engineering study is also reviewed which is crucial for future

Keywords： photocatalysis     overall water splitting     hydrogen    

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Research progress of defect-engineered UiO-66(Zr) MOFs for photocatalytic hydrogen production

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 656-666 doi: 10.1007/s11708-021-0765-9

Abstract: In recent years, defect-engineered Zr-based UiO-66 metal-organic frameworks (UiO-66(Zr) metal-organic frameworks (MOFs)) have shown huge advantages in catalytic, functional materials, adsorption, and other fields due to their large surface areas, well-ordered porous structures, and flexible tailorability. It is extremely challenging to introduce defect sites in the synthesis of MOFs to regulate the physicochemical properties of materials such as (energy band structure, pore structure, etc.) to obtain an excellent performance. This paper reviews the recent research results of synthesis methods, characterization technologies, and application fields of defect-engineered UiO-66(Zr) MOFs materials in order to provide new insights to synthesize high-performance UiO-66(Zr) MOFs materials and promote the development of UiO-66(Zr) in various fields.

Keywords： defect engineering     metal-organic frameworks     UiO-66     photocatalysis    

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Theoretical study on flow and radiation in tubular solar photocatalytic reactor

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 687-699 doi: 10.1007/s11708-021-0773-9

Abstract: mixture flow model, an optimized six-flux model is first established and applied to the tubular solar photocatalytic

Keywords： photocatalytic hydrogen photoreactor     nume- rical simulation     solar energy     flow model     radiation model    

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In-MOF-derived In2S3/Bi2S3 heterojunction for enhanced photocatalytichydrogen production

Frontiers in Energy 2023, Volume 17, Issue 5,   Pages 654-663 doi: 10.1007/s11708-023-0885-5

Abstract: for rationally designing innovative heterojunction photocatalysts of transition metal sulfides for photocatalytichydrogen production.

Keywords： photocatalytic hydrogen production     wide-spectrum response     metal sulfides     MOFs derivative     heterogeneous    

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A mini-review of ferrites-based photocatalyst on application of hydrogen production

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 621-630 doi: 10.1007/s11708-021-0761-0

Abstract: Photocatalytic water splitting for hydrogen production is a promising strategy to produce renewable energySpinel-ferrites are potential photocatalysts in photocatalytic reaction system due to their room temperature/sub> or g-C3N4 are also summarized to illustrate the advanced improvement in photocatalytichydrogen production.

Keywords： photocatalyst     spinel-ferrite     composite     photocatalytic hydrogen production    

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Metal-based direct hydrogen generation as unconventional high density energy

Shuo XU, Jing LIU

Frontiers in Energy 2019, Volume 13, Issue 1,   Pages 27-53 doi: 10.1007/s11708-018-0603-x

Abstract: Metals are unconventional hydrogen production materials which are of high energy densities.generation and the unconventional energy utilization ways thus enabled.Furthermore, the challenges lying behind this unconventional hydrogen generation method and energy strategyOverall, active metals like Na and K are appropriate for rapid hydrogen production occasions.Of these metals discussed, Al, Mg and their alloys offer the most promising hydrogen generation route

Keywords： metal     hydrogen generation     hydrolysis     metal water reaction     clean energy    

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Photocatalytic water splitting of ternary graphene-like photocatalyst for the photocatalytic hydrogen

Yan Zhang, Yuyan Zhang, Xue Li, Xiaohan Zhao, Cosmos Anning, John Crittenden, Xianjun Lyu

Frontiers of Environmental Science & Engineering 2020, Volume 14, Issue 4, doi: 10.1007/s11783-020-1248-7

Abstract: Abstract •The MoS2/SiC/GO composite has a strong photocatalytic activity than SiC.•GO acts as a bridge for electron passage in photocatalytic reaction.In the course finding possible solutions to this environmental canker, solar photocatalytic water splittingand GO as well as the temperature of hydrothermal reaction and their interactions on the evolution of hydrogenhydrogen production activity compared to that of pure SiC.

Keywords： Water splitting     Visible light     Graphene-like photocatalyst     Response surface methodology    

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Sulfur and carbon co-doped g-CN microtubes with enhanced photocatalytic H production activity

Frontiers in Energy doi: 10.1007/s11708-023-0899-z

Abstract: nitride (g-C3N4) has captured significant attention as a low-cost and efficient hydrogenaccelerating the separation of photogenerated carriers remain crucial strategies for promoting the photocatalyticMore importantly, co-doping S and C has greatly improved the photocatalytic performance of graphiticConsequently, the SCCN exhibits a remarkable photocatalytic H2 evolution rate of 4868 μmol

Keywords： carbon nitride     photocatalysis     hydrogen production    

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Alkali-thermal gasification and hydrogen generation potential of biomass

Alexander B. Koven, Shitang S. Tong, Ramin R. Farnood, Charles Q. Jia

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 3,   Pages 369-378 doi: 10.1007/s11705-017-1662-y

Abstract: Generating hydrogen gas from biomass is one approach to lowering dependencies on fossil fuels for energyMoreover, the concept of hydrogen generation potential (H -GP)—the maximum amount of H that a biomass

Keywords： hydrogen generation potential     biomass     lignocellulose     alkali-thermal gasification     sodium hydroxide    

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A preliminary study on the construction of wind and hydrogen power electric generating system

Xu Ye,Chen Xiaoning

Strategic Study of CAE 2010, Volume 12, Issue 11,   Pages 83-88

Abstract: To deal with the unstable stability of output power and the volatility of voltage in the wind power generation, a wind and hydrogen power electric generating system was put forward in the paper to break though thethe system, the controllable output, which corresponds to "valley"  of the wind power generationIn the mode, the "peak"  is used for hydrogen generation to "cut the peak"  and the "valley"  is used for electric power generation by hydrogen to "fill

Keywords： wind power generation     hydrogen power generation     hydrogen production and storage    

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Highly effective visible-photocatalytic hydrogen evolution and simultaneous organic pollutant degradation

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 10, doi: 10.1007/s11783-022-1566-z

Abstract:

● An urchin-like OMS/ZIS composite was fabricated by a facile solvothermal method.

Keywords： Dual-functional photocatalysts     Oxygen-doped MoS2/ZnIn2S4     H2 evolution     Organic pollutant    

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Title Author Date Type Operation

Novel strategies to tailor the photocatalytic activity of metal–organic frameworks for hydrogen generation

Luis A. ALFONSO-HERRERA, Leticia M. TORRES-MARTINEZ, J. Manuel MORA-HERNANDEZ

Journal Article

Enhanced hydrogen production from aqueous methanol solution using TiO

Paramasivan GOMATHISANKAR,Tomoko NODA,Hideyuki KATSUMATA,Tohru SUZUKI,Satoshi KANECO

Journal Article

Design and synthesis of ZnCoO/CdS for substantially improved photocatalytic hydrogen production

Journal Article

Function-reversible facets enabling SrTiO nanocrystals for improved photocatalytic hydrogen evolution

Journal Article

Recent advances of hydrogen production through particulate semiconductor photocatalytic overall water

Journal Article

Research progress of defect-engineered UiO-66(Zr) MOFs for photocatalytic hydrogen production

Journal Article

Theoretical study on flow and radiation in tubular solar photocatalytic reactor

Journal Article

In-MOF-derived In2S3/Bi2S3 heterojunction for enhanced photocatalytichydrogen production

Journal Article

A mini-review of ferrites-based photocatalyst on application of hydrogen production

Journal Article

Metal-based direct hydrogen generation as unconventional high density energy

Shuo XU, Jing LIU

Journal Article

Photocatalytic water splitting of ternary graphene-like photocatalyst for the photocatalytic hydrogen

Yan Zhang, Yuyan Zhang, Xue Li, Xiaohan Zhao, Cosmos Anning, John Crittenden, Xianjun Lyu

Journal Article

Sulfur and carbon co-doped g-CN microtubes with enhanced photocatalytic H production activity

Journal Article

Alkali-thermal gasification and hydrogen generation potential of biomass

Alexander B. Koven, Shitang S. Tong, Ramin R. Farnood, Charles Q. Jia

Journal Article

A preliminary study on the construction of wind and hydrogen power electric generating system

Xu Ye,Chen Xiaoning

Journal Article

Highly effective visible-photocatalytic hydrogen evolution and simultaneous organic pollutant degradation

Journal Article